PLGA-PEG-PLGA

PLGA-PEG-PLGA Triblock Copolymers – Biodegradable Thermo-Responsive Polymers for Advanced Drug Delivery

ResolveMass Laboratories Inc. provides high-purity PLGA-PEG-PLGA (poly(lactide-co-glycolide)-block-poly(ethylene glycol)-block-poly(lactide-co-glycolide)) triblock copolymers engineered for long-acting injectable systems, in-situ forming hydrogels, nanoparticle delivery platforms, and complex generic drug development.

This ABA triblock architecture combines:

Hydrophobic PLGA end blocks

A hydrophilic PEG mid-block

The resulting polymer exhibits thermo-responsive gelation, forming a sol at low temperature and transitioning into a stable gel at physiological temperature—ideal for sustained release depots and injectable gel formulations.

Key Features & Technical Advantages
1. Thermo-Responsive Sol-Gel Transition

PLGA-PEG-PLGA triblock copolymers undergo reversible sol-to-gel transition:

Injectable as a low-viscosity solution

Forms an in-situ gel at 35–37°C

Enables weeks to months of sustained drug release

We can tune the gelation temperature by adjusting:

PEG molecular weight

PLGA block length

Lactide:glycolide ratio

2. Customizable Molecular Weight & Composition

Available with fully customizable:

PEG block lengths (1–20 kDa)

PLGA block molecular weights (2–60 kDa each)

L:G ratios (50:50, 65:35, 75:25, or customer-specified)

This level of control allows optimized:

Depot formation

Release kinetics

Biodegradation rate

Solubility and mechanical properties

3. High-Purity Polymer for Controlled Release Formulation

Each batch is characterized using:

GPC/SEC with universal calibration

¹H/¹³C NMR for block identification and composition

FTIR for structural confirmation

DSC and TGA (optional) for thermal properties

MALDI-TOF or HRMS for end-group analysis (upon request)

These QC parameters support projects ranging from ANDA complex injectables to NDA enabling studies.

Applications
✔ Long-Acting Injectable Depots (In-Situ Gel Systems)

PLGA-PEG-PLGA forms biodegradable hydrogels suitable for:

Peptides (GLP-1 analogs, leuprolide, octreotide)

Proteins and biologics

Oligonucleotides

Hydrophobic and hydrophilic APIs

✔ Solubility Enhancement & Nanoparticle Formation

This amphiphilic architecture enables:

Self-assembly into micelles and nanoparticles

Enhanced aqueous compatibility

Improved pharmacokinetics

✔ Complex Generic Drug Delivery and 505(b)(2) Programs

Ideal for research involving:

Injectable gel depots

Biodegradable implants

Modified-release formulations for difficult APIs

✔ Custom Polymer Design for Novel Pharma R&D

We offer fully tailored polymer engineering for:

Thermo-responsive injectable gels

High-drug-loading micelles

Stabilization of sensitive biomolecules

Why Choose ResolveMass Laboratories Inc.?
✔ Specialized Expertise in Biodegradable Block Copolymers

Our team routinely synthesizes:

PLGA-PEG-PLGA

mPEG-PLGA

PLA-PEG-PLA

PCL-PEG-PCL

Fully customized block copolymers

✔ Advanced Characterization Infrastructure

Including:

Triple-detector GPC

HRMS & LC-MS/MS

MALDI-TOF

DSC/TGA

High-field NMR

✔ Formulation-Driven Polymer Engineering

We focus on polymer performance needed for CMC, complex generics, biosimilar depot systems, and novel delivery platforms.

Available Grades

Standard research grade

High-purity grade for formulation development

Custom synthesized to target molecular weight & gelation profile

Request Custom PLGA-PEG-PLGA Specifications

Our chemistry team can design triblock copolymers with precise molecular architecture, tailored for your long-acting injectable or controlled-release innovation.

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